Correct option is B
For the formation of the product A, COOH and benzyl (Bn) group must be in the same plane. Also, the two phenyl groups are anti to each other which can be seen from the Newman projection in image shown.

The conformer of threo-2,3,4-triphenylbutyric acid that gives the product A in the presence of anhydrous HF is

For the formation of the product A, COOH and benzyl (Bn) group must be in the same plane. Also, the two phenyl groups are anti to each other which can be seen from the Newman projection in image shown.

The correct statement for the orientation of the bromine atoms in the most stable conformations of A and B is

The stereochemical relationship of Ha and Hb in the following molecule is

The correct relationship between the two faces of the C=O group in compounds A and B is

A compound shows [M]+at m/z 84 and has a base peak at 56. It exhibits only one signal in 1H NMR at δ 1.4ppm and one single in 13C NMR at δ 35ppm. The compound is
The Newman projection given below

corresponds to the compound
Given the specific rotation of (S)-4-methyl-3 heptanone in hexane as +22o, the specific rotation , in hexane, of the product A (ee=98%) obtained from the following enantioselective alkylation reaction is

The correct relationship between the following structures is that they are

The structure that corresponds to the most stable conformation of the following compound is

The products of the following reaction of a sample of 2-butanol (ee=X%) show two doublets in 1H NMR spectrum in the ratio of 3:2. The value of X is

The difference between the lowest energy and the next higher energy conformers (in kcal mol-1) of meso-2, 3-dibromobutane is
