hamburger menu
All Coursesall course arrow
adda247
reward-icon
adda247
    arrow
    arrow
    arrow
    Given the specific rotation [α]D20[\alpha]^{20}_D[α]D20​ of (S)-4-methyl-3 heptanone in hexane as +22o, ​the specific rotation [α]
    Question

    Given the specific rotation [α]D20[\alpha]^{20}_D of (S)-4-methyl-3 heptanone in hexane as +22o​the specific rotation [α]D20[\alpha]^{20}_Din hexane, of the product A (ee=98%) obtained from the following enantioselective alkylation reaction is


    A.

    +21.56

    B.

    +21.12

    C.

    -21.56

    D.

    -21.12

    Correct option is C

    ​In chemistry, specific rotation ([α]) is a property of a chiral chemical compound. It is defined as the change in orientation of monochromatic plane-polarized light, per unit distance–concentration product, as the light passes through a sample of a compound in solution. Compounds which rotate the plane of polarization of a beam of plane polarized light clockwise are said to be dextrorotary, and correspond with positive specific rotation values, while compounds which rotate the plane of polarization of plane polarized light counterclockwise are said to be levorotary, and correspond with negative values. If a compound is able to rotate the plane of polarization of plane-polarized light, it is said to be “optically active”.

    Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.

    If the specific rotation,​

    of a pure chiral compound is known, it is possible to use the observed specific rotation,[α]obs{\displaystyle {[\alpha ]_{\text{obs}}}}
    to determine the enantiomeric excess (ee), or "optical purity", of a sample of the compound, by using the formula:

    The given product is chiral. Chiral molecules will usually have a stereogenic element from which chirality arises. The most common type of stereogenic element is a stereogenic center, or stereocenter. In the case of organic compounds, stereocenters most frequently take the form of a carbon atom with four distinct (different) groups attached to it in a tetrahedral geometry.

    test-prime-package

    Access ‘CSIR NET Chemical Sciences’ Mock Tests with

    • 60000+ Mocks and Previous Year Papers
    • Unlimited Re-Attempts
    • Personalised Report Card
    • 500% Refund on Final Selection
    • Largest Community
    students-icon
    383k+ students have already unlocked exclusive benefits with Test Prime!
    test-prime-package

    Access ‘CSIR NET Chemical Sciences’ Mock Tests with

    • 60000+ Mocks and Previous Year Papers
    • Unlimited Re-Attempts
    • Personalised Report Card
    • 500% Refund on Final Selection
    • Largest Community
    students-icon
    383k+ students have already unlocked exclusive benefits with Test Prime!
    Our Plans
    Monthsup-arrow