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    The predicted rate law, using the steady state approximation, for the reaction ​
    Question

    The predicted rate law, using the steady state approximation, for the reaction 


    A.

    B.

    C.

    D.

    Correct option is A

    Consecutive or Sequential reactions

    In many cases the product formed in one of the elementary reactions acts as the reactant for some other elementary reaction.

    Steady-State Approximation

    Figures a and b illustrate the typical variations in the concentrations of A,B and C for the two consecutive first-order reactions with 

    In figure a, the concentration of A disappears very rapidly as 

    and since the rate at which B disappears is relatively slow, the concentration of B increases rapidly and after attaining the maximum in a small time interval, starts decreasing.

    In figure b, the concentration of A decreases slowly as the reaction rate constant k1 has a small value. The concentration of B practically remains constant for a reasonable length of time during the reaction, except at the very beginning and at the end. This constancy results from the fact that the intermediate B is very reactive as its transformation to C occurs at a very fast rate. In fact, the concentration of B at any instant will be much smaller than that of A.

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