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    Consider the statements about the following species,​​
    Question

    Consider the statements about the following species,



    A.

    B.

    C.

    D.

    Correct option is B

    Valence shell electron pair repulsion (VSEPR) theory is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. The premise of VSEPR is that the valence electron pairs surrounding an atom tend to repel each other. The greater the repulsion, the higher in energy (less stable) the molecule is. Therefore, the VSEPR-predicted molecular geometry of a molecule is the one that has as little of this repulsion as possible.
    VSEPR theory is used to predict the arrangement of electron pairs around central atoms in molecules, especially simple and symmetric molecules. A central atom is defined in this theory as an atom which is bonded to two or more other atoms, while a terminal atom is bonded to only one other atom.
    The overall geometry is further refined by distinguishing between bonding and nonbonding electron pairs. The bonding electron pair shared in a sigma bond with an adjacent atom lies further from the central atom than a nonbonding (lone) pair of that atom, which is held close to its positively charged nucleus. VSEPR theory therefore views repulsion by the lone pair to be greater than the repulsion by a bonding pair. As such, when a molecule has 2 interactions with different degrees of repulsion, VSEPR theory predicts the structure where lone pairs occupy positions that allow them to experience less repulsion. Lone pair–lone pair (lp–lp) repulsions are considered stronger than lone pair–bonding pair (lp–bp) repulsions, which in turn are considered stronger than bonding pair–bonding pair (bp–bp) repulsions, distinctions that then guide decisions about overall geometry when 2 or more non-equivalent positions are possible
    The electronic geometry of a molecule depends on the number of bond pairs and lone pairs, while the shape depends only on the number of bond pairs.
    The steric number of a central atom in a molecule is the number of atoms bonded to that central atom, called its coordination number, plus the number of lone pairs of valence electrons on the central atom.

    Total lone pairs of electrons on the chlorine atoms in the five species is 9.

    The shape of [ClF4]+ion is see saw. The name "seesaw" comes from the observation that it looks like a playground seesaw. The seesaw shape occurs when a molecule has a steric number of 5, with the central atom being bonded to 4 other atoms and 1 lone pair. An equatorial lone pair is repelled by only two bonding pairs at 90°, whereas a hypothetical axial lone pair would be repelled by three bonding pairs at 90° which would make the molecule unstable. Repulsion by bonding pairs at 120° is much smaller and less important.

    Chlorine trifluoride is an interhalogen compound with the formula ClF3. It is a colorless, poisonous, corrosive, and extremely reactive gas that condenses to a pale-greenish yellow liquid, the form in which it is most often sold (pressurized at room temperature).ClF3 is used for the fluorination of a variety of compounds.



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