arrow
arrow
arrow
Consider the following statements for Allred- Rochow electronegativity (χAR):i. χAR is directly proportional to Zeff. ii. χAR is inversely p
Question

Consider the following statements for Allred- Rochow electronegativity (χAR):

i. χAR is directly proportional to Zeff.
ii. χAR is inversely proportional to Zeff
iii. χAR is inversely proportional to r (covalent)
iv. χAR is inversely proportional to r2(covalent)
The correct statements are


A.

i and iv

B.

ii and iv

C.

i and iii

D.

ii and iii

Correct option is A

​Allred and Rochow chose as a measure of electronegativity of an atom the electrostatic force exerted by the effective nuclear charge Zeff on the valence electrons. The latter are assumed to reside at a distance from the nucleus equal to the covalent radius, rcov, of the atom. Equation gives the method of calculating values of the Allred–Rochow electronegativity.

χAR=(3590×Zeffrcov2)+0.744wherercov is in pm\chi^{AR} = \left( 3590 \times \frac{Z_{\text{eff}}}{r_{\text{cov}}^2} \right) + 0.744 \quad \text{where} \quad r_{\text{cov}} \, \text{is in pm}

Similar Questions

test-prime-package

Access ‘CSIR NET Chemical Sciences’ Mock Tests with

  • 60000+ Mocks and Previous Year Papers
  • Unlimited Re-Attempts
  • Personalised Report Card
  • 500% Refund on Final Selection
  • Largest Community
students-icon
353k+ students have already unlocked exclusive benefits with Test Prime!
test-prime-package

Access ‘CSIR NET Chemical Sciences’ Mock Tests with

  • 60000+ Mocks and Previous Year Papers
  • Unlimited Re-Attempts
  • Personalised Report Card
  • 500% Refund on Final Selection
  • Largest Community
students-icon
353k+ students have already unlocked exclusive benefits with Test Prime!
Our Plans
Monthsup-arrow