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    Consider the following statements for Allred- Rochow electronegativity (χAR):i. χAR is directly proportional to Zeff. ii. χAR is inversely p
    Question

    Consider the following statements for Allred- Rochow electronegativity (χAR):

    i. χAR is directly proportional to Zeff.
    ii. χAR is inversely proportional to Zeff
    iii. χAR is inversely proportional to r (covalent)
    iv. χAR is inversely proportional to r2(covalent)
    The correct statements are


    A.

    i and iv

    B.

    ii and iv

    C.

    i and iii

    D.

    ii and iii

    Correct option is A

    ​Allred and Rochow chose as a measure of electronegativity of an atom the electrostatic force exerted by the effective nuclear charge Zeff on the valence electrons. The latter are assumed to reside at a distance from the nucleus equal to the covalent radius, rcov, of the atom. Equation gives the method of calculating values of the Allred–Rochow electronegativity.

    χAR=(3590×Zeffrcov2)+0.744wherercov is in pm\chi^{AR} = \left( 3590 \times \frac{Z_{\text{eff}}}{r_{\text{cov}}^2} \right) + 0.744 \quad \text{where} \quad r_{\text{cov}} \, \text{is in pm}

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