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    The number-average degree of polymerization of self-catalyzed polyesterification, a 3rd order reaction, is expressed as [[M]₀: initial monomer conce
    Question



    The number-average degree of polymerization

    of self-catalyzed polyesterification, a 3rd order reaction, is expressed as [[M]₀: initial monomer concentration]

    A.

    B.

    C.

    D.

    Correct option is A


    The number-average degree of polymerization (Xn) describes the average number of monomer units in a polymer chain. In the case of a self-catalyzed polyesterification reaction, which is a third-order reaction, the degree of polymerization can be derived based on the reaction kinetics and the initial monomer concentration.
    Polymerization Kinetics:
    • For a third-order reaction, the rate of reaction is proportional to the cube of the concentration of the monomer.
    • The number-average degree of polymerization (Xn) increases as the monomers react to form polymer chains, and it depends on the initial monomer concentration ([M]o) and the rate constant (k).

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