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Based on Derjaguin, Landau, Verwey and Overbeek (DLVO) theory, the stability of colloids depends on
Question



Based on Derjaguin, Landau, Verwey and Overbeek (DLVO) theory, the stability of colloids depends on

A.

only electrical double layer repulsion.

B.

only van der Waals attraction.

C.

electrical double layer repulsion and van der Waals attraction.

D.

electrical double layer and van der Waals attractions.

Correct option is C

The Derjaguin–Landau–Verwey–Overbeek (DLVO) theory explains the aggregation and kinetic stability of aqueous dispersions quantitatively and describes the force between charged surfaces interacting through a liquid medium. DLVO theory is a theory of colloidal dispersion stability in which zeta potential is used to explain that as two particles approach one another their ionic atmospheres begin to overlap and a repulsion force is developed. Zeta potential is the potential difference between the dispersion medium and the stationary layer of fluid attached to the dispersed particle.
In this theory, two forces are considered to impact on colloidal stability: Van der Waals forces and electrical double layer forces. The total potential energy is described as the sum of the attraction potential and the repulsion potential. When two particles approach each other, electrostatic repulsion increases and the interference between their electrical double layers increases. However, the Van der Waals attraction also increases as they get closer. At each distance, the net potential energy of the smaller value is subtracted from the larger value.

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