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The base ionization constant, Kb, of ammonia in water is 1.8×10−51.8×10^{-5}1.8×10−5. ​The value of acid ionization constant, Ka, 
Question

The base ionization constant, Kb, of ammonia in water is 1.8×1051.8×10^{-5}​The value of acid ionization constant, Ka, of the conjugate acid is closest to


A.

5.6×10105.6×10^{-10}​​

B.

1.8×1091.8×10^{9}​​

C.

7.0×1077.0×10^{-7}​​

D.

5.6×1045.6×10^{4}​​

Correct option is A

For ammonia (NH3) and its conjugate acid ammonium ion (NH4+), we have the following equilibrium reactions in water:

NH3+H2ONH4++OH\text{NH}_3 + \text{H}_2\text{O} \rightleftharpoons \text{NH}_4^+ + \text{OH}^-

The base ionization constant, Kb, is given as 1.8×10-5. It represents the equilibrium constant for the reaction of ammonia with water to form ammonium ions and hydroxide ions. The acid ionization constant, Ka, for the conjugate acid ammonium ion (NH4+), is related to Kb through the following expression:

Ka×Kb=KwK_a×K_b=K_w

where Kis the ionic product constant for water at a given temperature, which is approximately 1.0×10-14 at room temperature. The value of Ka can be calculated as follows:

Ka×Kb=KwK_a×K_b=K_w

or, Ka×(1.8×105)=1.0×1014K_a×(1.8×10{-5})=1.0×10^{-14}

or, Ka=(1.0×1014)/(1.8×105)K_a=(1.0×10^{-14})/(1.8×10^{-5})​ 

or, Ka5.6×1010K_a \approx 5.6×10^{-10}


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