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The following statements are given with respect to the symmetry operations and symmetry elements. A. BF3 possesses an S3 axis B. C2H6 in a stagg
Question



The following statements are given with respect to the symmetry operations and symmetry elements.
A. BF3 possesses an S3 axis

B. C2H6 in a staggered conformation possesses an S6 axis
C. Benzene molecule possesses three σv - planes
D. Water molecule possesses C2 axis and σh - plane
The option giving the correct statements, is

A.


B.


C.


D.


Correct option is B

The systematic discussion of symmetry is called group theory. An action that leaves an object looking the same after it has been carried out is called a symmetry operation. Typical symmetry operations include rotations, reflections, and inversions. There is a corresponding symmetry element for each symmetry operation, which is the point, line, or plane with respect to which the symmetry operation is performed.
The classification of objects according to symmetry elements corresponding to operations that leave at least one common point unchanged gives rise to the point groups.
The identity, E, consists of doing nothing; the corresponding symmetry element is the entire object.
An n-fold rotation (the operation) about an n-fold axis of symmetry, Cn (the corresponding element) is a rotation through 360°/n. If a molecule possesses several rotation axes, then the one (or more) with the greatest value of n is called the principal axis.

A reflection (the operation) in a mirror plane, σ (the element), may contain the principal axis of a molecule or be perpendicular to it. If the plane is parallel to the principal axis, it is called ‘vertical’ and denoted σv . A vertical mirror plane that bisects the angle between two C2 axes is called a ‘dihedral plane’ and is denoted σd . When the plane of symmetry is perpendicular to the principal axis it is called ‘horizontal’ and denoted σh.
An n-fold improper rotation (the operation) about an n-fold axis of improper rotation or an n-fold improper rotation axis, Sn, (the symmetry element) is composed of two successive transformations. The first component is a rotation through 360°/ n, and the second is a reflection through a plane perpendicular to the axis of that rotation; neither operation alone needs to be a symmetry operation.
If in addition to the identity and a Cn axis a molecule has n vertical mirror planes σv , then it belongs to the group Cnv.
A molecule that has an n-fold principal axis and n two fold axes perpendicular to Cn belongs to the group Dn. A molecule belongs to Dnh if it also possesses a horizontal mirror plane.
A molecule belongs to the group Dnd if in addition to the elements of Dn it possesses n dihedral mirror planes σd. The staggered conformation of ethane belongs to D3d.

Benzene  belongs to D6h . The symmetry elements are:

Figure shows all the symmetry elements for the water molecule. By convention, the rotation axis of highest symmetry (principal rotation axis), C2 , is oriented along the z axis. The C2 axis passes through the O atom. The molecule has two mirror planes oriented at 90° to one another, and their line of intersection is the C2 axis.

BF3 belongs to D3h .The symmetry elements are:

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