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    A molecule absorbs light at ‘X’ nm wavelength and emits light as fluorescence at ‘Y’ nm wavelength. Typically, there is a shift in the wavelength (Y&g
    Question

    A molecule absorbs light at ‘X’ nm wavelength and emits light as fluorescence at ‘Y’ nm wavelength. Typically, there is a shift in the wavelength (Y>X). E is the energy transferred to the solvent during reorganization of the excited state, ‘h’ is the Planck’s constant, and ‘c’ is the speed of light.

    E is equal to:

    A.

    h(Y-X)

    B.

    hc(Y-X) / XY

    C.

    c(Y-X) / h

    D.

    c / (Y-X)

    Correct option is B

    EXPLANATION-

    To solve this, let's start by recalling the relationship between energy and wavelength in light:

    E=hcλE = \frac{hc}{\lambda}

    Where:
     is the energy,
    ℎ  is Planck’s constant,
      is the speed of light,
     is the wavelength of light.

    The energy difference between absorbed and emitted light (i.e., energy lost to the environment during relaxation) is:

                                                                                                    E=hcXhcYE = \frac{hc}{X} - \frac{hc}{Y}

    Taking common factor hc:hc\text{:}

                                                                  E=hc(1X1Y)=hcYXXYE = hc\left( \frac{1}{X} - \frac{1}{Y} \right) = hc \frac{Y - X}{XY}

    So, the correct option is (b) hc(Y-X) / XY

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