Question

What is the pH of a 10^(-7) M solution of HCl?

A.

​6.00

B.

6.79

C.

7.00

D.

7.50

Correct option is B

Given:

  • Concentration of HCl = 10-7M
  • Auto-ionization of water must be considered since the concentration of HCl is very low.

Step 1: Consider the Contribution of Water

Water itself ionizes to give:

H2O⇌H++OH-

The concentration of H+H^+H+ from water is:

[H+]water =10-7M

Since HCl is a strong acid, it completely dissociates:

HCl→ H+ Cl-

So, the total hydrogen ion concentration is:

[H+]total = [H+]water + [H+] HCl

= 10-7 + 10-7 

2×107 M2 \times 10^{-7} \, M

Step 2: Calculate pH

pH=−log⁡[H+]

pH=log(2×10-7)

Using logarithm properties:

log(2×10-7)=log2+log10-7

Approximating log⁡2≈0.301\log 2 \approx 0.301log20.301:

pH=−(0.301−7)\text{pH} = -(0.301 - 7)pH=(0.3017)pH=6.70≈6.79\text{pH} = 6.70 \approx 6.79pH

=6.706.79

Correct Answer:

(2) 6.79


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