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    ​The units of molar extinction coefficient are:​
    Question

    The units of molar extinction coefficient are:

    A.

    L mol⁻¹ cm⁻¹

    B.

    cm⁻¹ mg mL⁻¹

    C.

    mol⁻¹ mm

    D.

    mol cm mL⁻¹

    Correct option is A

    Explanation-

    The molar extinction coefficient (also called molar absorptivity, denoted by ε) is a constant that relates how strongly a chemical species absorbs light at a given wavelength.

    It appears in Beer-Lambert Law:

    A=εclA = \varepsilon \cdot c \cdot l

    Where:
    = Absorbance (unitless)
     = Molar extinction coefficient
      = Concentration of the solution (mol/L)
     = Path length of the cuvette (cm)

    Rearranging the equation:
                                    ε=Acl\varepsilon = \frac{A}{c \cdot l}​​
    ​Since:
    Absorbance (A) has no units,
    Concentration (c) has units mol/L,
    Path length (l) has units cm,
    Substitute the units into the formula:

                                               ε=1mol/Lcm=Lmolcm\varepsilon = \frac{1}{\text{mol/L} \cdot \text{cm}} = \frac{L}{\text{mol} \cdot \text{cm}} = L mol⁻¹ cm⁻¹

    L: Liters — unit of volume
    mol⁻¹: Per mole — unit of amount of substance
    cm⁻¹: Per centimeter — unit of path length
    This unit tells you how much light is absorbed per mole of substance in 1 liter solution over a 1 cm path length.

    Final answer - option a : L mol⁻¹ cm⁻¹

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