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The number of σ bonds, π-bonds and the total bonds in benzene molecule. respectively, are:
Question

The number of σ bonds, π-bonds and the total bonds in benzene molecule. respectively, are:

A.

12, 3, 15

B.

6, 3, 15

C.

6, 6, 18

D.

6, 6, 12

Correct option is A

The correct answer is option ( a ) 12, 3, 15

Given :  Benzene molecule  (C6H6)(C_6H_6)​​

  • Benzene is a hexagonal ring structure with 6 carbon atoms and 6 hydrogen atoms.
  • Each carbon is bonded to:
    1. One hydrogen atom via a σ-bond.
    2. Two neighboring carbon atoms via one σ-bond each.
    3. Alternating double bonds form π-bonds.

Count the σ-bonds :

  1. C - H σ-bonds :  6
  2. C - C σ-bonds :  6

Total σ-bonds=6(C-H)+6(C-C)=12\text{Total } \sigma \text{-bonds} = 6 \, (\text{C-H}) + 6 \, (\text{C-C}) = 12Total σ-bonds=6(C-H)+6(C-C)=12

Count thπ-bonds :

  • The alternating double bonds in benzene consist of 3 π-bonds, one for each double bond.

Total π-bonds=3\text{Total } \pi \text{-bonds} = 3Total π-bonds=3

Count thtotal bonds :

Total bonds=σ-bonds+π-bonds=12+3=15\text{Total bonds} = \text{σ-bonds} + \text{π-bonds} = 12 + 3 = 15   Total bonds=σ-bonds+π-bonds=12+3=15

σ-bonds: 121212

π-bonds: 333

Total bonds: 151515

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