hamburger menu
All Coursesall course arrow
adda247
reward-icon
adda247
    arrow
    arrow
    arrow
    Aniline does not undergo Friedel-Crafts reaction because (A) It forms salt with the Lewis acid catalyst, AlCl_3. (B) Nitrogen of aniline acquires
    Question

    Aniline does not undergo Friedel-Crafts reaction because
    (A) It forms salt with the Lewis acid catalyst, AlCl_3.
    (B) Nitrogen of aniline acquires negative charge.
    (C) Nitrogen of aniline acquires positive charge.
    (D) Nitrogen acts as a strong deactivating group in the further reaction.
    Choose the correct answer from the options given below :

    A.

    (A), (B) and (D) only

    B.

    (A), (B) and (C) only

    C.

    (A), (C) and (D) only

    D.

    (B), (C) and (D) only

    Correct option is C

    Aniline, N-substituted and N,N-disubstituted anilines do not undergo Friedel-Craft's reactions due to salt formation with aluminium chloride which is used as a Lewis acid catalyst. Positive charge on nitrogen is strongly electron-withdrawing and thus deactivates the ring for further acylation or alkylation reactions.

    Free Tests

    Free
    Must Attempt

    CUET 2025 English Language Mock 01

    languageIcon English
    • pdpQsnIcon50 Questions
    • pdpsheetsIcon200 Marks
    • timerIcon45 Mins
    languageIcon English