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    N₃H is represented as Nitrogen attached with double bonds has oxidation number:
    Question

    N₃H is represented as

    Nitrogen attached with double bonds has oxidation number:

    A.

    0

    B.

    +3

    C.

    –2

    D.

    –3

    Correct option is B


    The correct answer is: (b) +3
    Oxidation Number of Nitrogen with Double Bonds in Hydrazoic Acid (HN₃):
    Hydrazoic acid has the molecular formula HN₃, and one of its resonance structures is:
    H–N⁻=N⁺=N
    In this structure:
    · The first nitrogen is bonded to hydrogen and another nitrogen: usually has oxidation number –3.
    · The third nitrogen has a negative formal charge: oxidation number –1.
    · The central nitrogen is double bonded to both adjacent nitrogen atoms, and carries a positive charge.
    To calculate the oxidation state of the central nitrogen:
    Let the oxidation numbers be:
    · First N (bonded to H) = –3
    · Third N = –1
    · Central N = x
    · Hydrogen = +1
    Using the rule that the total oxidation number in a neutral compound is 0:
    (+1) + (–3) + x + (–1) = 0 → x = +3

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