Gadolinium belongs of 4f series. Its atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?

Although chlorine is an electron withdrawing group, yet it is ortho- and para-directing in electrophilic aromatic substitution reaction because
(A) Chlorine withdraws electrons through inductive effect.
(B)Chlorine destabilises the intermediate carbocation formed during electrophilic substitution.
(C) Chlorine accepts electrons through resonance.
(D) Chlorine releases electrons through resonance.
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In Etard reaction, the final product is

Aniline does not undergo Friedel-Crafts reaction because
(A) It forms salt with the Lewis acid catalyst, AlCl_3.
(B) Nitrogen of aniline acquires negative charge.
(C) Nitrogen of aniline acquires positive charge.
(D) Nitrogen acts as a strong deactivating group in the further reaction.
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Match List-I with List-II:

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Match List-I with List-II:

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Match List-I with List-II:

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