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By which unit do the successive members of the homogenous series CH4_44​​, C2_22​​H6_66​​, and C3_33​​H8_88​​differ from each other?
Question

By which unit do the successive members of the homogenous series CH4_4​, C2_2​H6_6​, and C3_3​H8_8​differ from each other?

A.

CH3_3​​

B.

CH

C.

CH4_4​​

D.

CH2_2​​

Correct option is D

The correct answer is: (D) CH₂
Explanation:
The compounds CH₄ (methane), C₂H₆ (ethane), and C₃H₈ (propane) form a homologous series of alkanes, where each successive member differs by the addition of a CH₂ (methylene) unit.
  • Methane (CH₄) is the first member of the series.

  • Ethane (C₂H₆) is formed by adding one CH₂ unit to methane.

  • Propane (C₃H₈) is formed by adding another CH₂ unit to ethane.

This CH₂ unit is the building block for each successive member of the alkane series, where the number of carbon atoms increases by one and the number of hydrogen atoms increases by two for each successive compound.
Information Booster:
  • Alkanes follow the general formula CₙH₂ₙ₊₂, and this pattern of increasing by CH₂ is consistent across the series.

  • Alkanes are saturated hydrocarbons, meaning they contain only single bonds between carbon atoms.

  • The differences in molecular structure between members of a homologous series lead to differences in physical properties such as boiling points and melting points.

  • CH₂ is the simplest structural unit in this case, used in the construction of larger molecules in the series.

Additional Information:

  • CH₃: This is the methyl group, which is the unit by which successive members of the homologous series of alkanes (like CH₄, C₂H₆, C₃H₈) differ. Each member of the series differs by one CH₃ group.

  • CH: This would refer to a methylene group, but it is not the unit by which successive alkanes differ. Instead, CH₂ groups are often seen in alkenes and other unsaturated hydrocarbons.

  • CH₄: This is methane, the simplest alkane, and does not represent the unit by which other alkanes differ in the homologous series. 

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