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A mixture of 0.6 mol of hexane and 0.4 mol of nitrobenzene was prepared at 300 K. Based on the phase diagram given below, the number of moles of hexan
Question



A mixture of 0.6 mol of hexane and 0.4 mol of nitrobenzene was prepared at 300 K. Based on the phase diagram given below, the number of moles of hexane in α phase is [α phase: hexane rich phase, β phase: nitrobenzene rich phase]

A.

0.56

B.

0.42

C.

0.38

D.

0.32

Correct option is A

The phase diagram shows the equilibrium composition of the two phases, α (hexane-rich) and β (nitrobenzene-rich), at 300 K.


The lever rule is a formula used to determine the mole fraction (xi) of each phase of a binary equilibrium phase diagram. It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
The total moles of mixture = 0.6 mol hexane + 0.4 mol nitrobenzene = 1.0 mol.
Let nα​ and nβ​ be the number of moles in the α and β phases, respectively.
Using the lever rule:

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