Correct option is D
✅ (d) 680 nm: • Chlorophyll 'a' absorbs red light most efficiently, especially around 680 nm. • This corresponds to Photosystem II (P680) in the light reaction of photosynthesis. • Also absorbs in the blue region (430–450 nm).
❌ (a), (b), (c): • 480 nm is more for chlorophyll b or accessory pigments; 580–600 nm is less efficiently absorbed.