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    Which of the following statements is correct regarding chromium in water?
    Question



    Which of the following statements is correct regarding chromium in water?

    A.

    Chromium (III) is less likely to be found in a soluble form than Chromium (VI).

    B.

    Chromium (III) toxicity in electroplating wastewaters is decreased by oxidation to Chromium (VI).

    C.

    Chromium is not an essential trace element.

    D.

    Chromium is known to form methylated species analogous to methyl mercury compounds.

    Correct option is A


    Chromium in water primarily exists in two oxidation states: Chromium (III) and Chromium (VI).
    Chromium (III):
    · Found in insoluble forms due to its strong tendency to form precipitates or associate with organic matter.
    · Less soluble compared to Chromium (VI).
    Chromium (VI):
    · Highly soluble and mobile in water.
    · It is also more toxic and carcinogenic compared to Chromium (III).
    Information Booster: · Chromium Sources: Found in industrial waste (electroplating, leather tanning) and natural weathering.
    · Environmental Impact of Chromium:
    · Chromium (VI) is a major pollutant due to its toxicity.
    · Chromium (III) is less toxic and often used as a dietary supplement.
    · Reduction Pathways: Chromium (VI) can be reduced to Chromium (III) using reducing agents (e.g., ferrous sulfate), which decreases its toxicity.
    · Health Impact:
    · Chromium (VI): Carcinogenic and affects respiratory and gastrointestinal systems.
    · Chromium (III): Necessary in trace amounts but toxic in higher doses.
    Additional Knowledge: 1. Chromium (III):
    · Stable in reducing environments.
    · Precipitates easily as chromium hydroxides.
    2. Chromium (VI):
    · Stable in oxidizing environments.
    · Commonly present in the form of chromate (CrO₄²⁻) or dichromate (Cr₂O₇²⁻).
    3. Regulation Limits:
    · Drinking water standards typically limit Chromium (VI) to 0.05 mg/L due to its toxicity.
    4. Applications of Chromium:
    · Chromium (III): Tanning leather.
    · Chromium (VI): Used in pigments, metal plating, and stainless steel production.

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