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The electrical conductivity of a metal decreases with increasing temperature, because
Question

The electrical conductivity of a metal decreases with increasing temperature, because

A.

the energy of electrons increases with increasing temperature

B.

metal increases on heating

C.

metal atoms vibrate more at high temperature

D.

metals have low specilis heat

E.

None of the above/More than one of the above

Correct option is C

The correct answer is (c) metal atoms vibrate more at high temperature

Explanation:
• In standard metallic conductors, electrical current is driven by the smooth flow of free delocalized electrons.
• As the temperature systematically increases, the positive metal ions (atoms) in the lattice structure vibrate more vigorously with heightened amplitude.
• This intense vibration vastly increases the frequency of collisions between the drifting electrons and the ions, restricting their flow and hence decreasing electrical conductivity.

Information Booster:
• The resistance of a metal linearly increases with temperature. This principle is utilized effectively in designing resistance thermometers.
• In stark contrast, the conductivity of semiconductors (like Silicon) actually increases with temperature because thermal energy excites more electrons into the conduction band.

Additional Knowledge:
the energy of electrons increases with increasing temperature (Option a)
• While their thermal velocity increases, the chaotic motion does not aid a directional drift current; it is the lattice vibration that fundamentally causes the resistance.
metal increases on heating (Option b)
• Thermal expansion (the volume increase) occurs but is not the primary physical reason for diminished conductivity.
metals have low specilis heat (Option d)
• Specific heat capacity dictates how much energy is needed to raise temperature, entirely unrelated to the mechanics of electrical resistance.
None of the above/More than one of the above (Option e)
• Incorrect, as lattice vibration is the fundamental accepted answer.

So the correct answer is (c)

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