Correct option is D
Given reaction:
FeSO4(s)→Fe2O3(s)+SO2(g)+SO3(g)\text{FeSO}_4 (s) \rightarrow \text{Fe}_2\text{O}_3 (s) + \text{SO}_2 (g) + \text{SO}_3 (g)FeSO4(s)→Fe2O3(s)+SO2(g)+SO3(g)
Step-by-step balancing:
Balance the iron atoms:
- On the left side, there is 1 Fe atom (in FeSO₄).
- On the right side, Fe is present in Fe₂O₃, where there are 2 Fe atoms.
- To balance Fe, put a coefficient of 2 in front of FeSO₄ on the left side:2FeSO4→Fe2O3+SO2+SO32 \text{FeSO}_4 \rightarrow \text{Fe}_2\text{O}_3 + \text{SO}_2 + \text{SO}_32FeSO4→Fe2O3+SO2+SO3
Balance the sulfur atoms:
- On the left side, there are 2 sulfur atoms (in 2 FeSO₄).
- On the right side, sulfur is present in SO₂ and SO₃.
- Put a coefficient of 2 in front of SO₂ to balance sulfur:2FeSO4→Fe2O3+2SO2+SO32 \text{FeSO}_4 \rightarrow \text{Fe}_2\text{O}_3 + 2 \text{SO}_2 + \text{SO}_32FeSO4→Fe2O3+2SO2+SO3
Balance oxygen atoms:
- On the left side, there are 8 oxygen atoms (in 2 FeSO₄).
- On the right side:
- Fe₂O₃ has 3 oxygen atoms.
- 2 SO₂ has 4 oxygen atoms.
- SO₃ has 3 oxygen atoms.
- Total oxygen atoms on the right side = 3 (from Fe₂O₃) + 4 (from 2 SO₂) + 3 (from SO₃) = 10.
- Therefore, to balance oxygen, we add a coefficient of 1 in front of SO₃:2FeSO4→Fe2O3+2SO2+SO32 \text{FeSO}_4 \rightarrow \text{Fe}_2\text{O}_3 + 2 \text{SO}_2 + \text{SO}_32FeSO4→Fe2O3+2SO2+SO3
Thus, the correct set of values for p, q, r, s is:
- p = 2 (for FeSO₄)
- q = 1 (for Fe₂O₃)
- r = 2 (for SO₂)
- s = 1 (for SO₃)
So the correct answer is (D) 2, 1, 1, 1.