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    Calculate the residence time of chemical species in the atmosphere having a mixing ratio of 1 part per billion (ppb) by mass. Given: Total flu
    Question



    Calculate the residence time of chemical species in the atmosphere having a mixing ratio of 1 part per billion (ppb) by mass.
    Given: Total flux of species (natural and anthropogenic sources) is 200×1012 g/year, and the mass of the atmosphere is 4×1021 g.

    A.

    ~ 0.1 week

    B.

    ~ 1 week

    C.

    ~ 10 weeks

    D.

    ~ 50 weeks

    Correct option is B


    The residence time of a species is calculated using the formula:

    Step-by-Step Solution: 1. Mass of the Species in the Atmosphere: The species' mixing ratio is 1 ppb=1×10−9, and the total mass of the atmosphere is 4×1021 g:
    Mass of species=1×10−9×4×1021=4×1012 g
    2. Residence Time Calculation: Using the formula and substituting values:

    3. Convert to Weeks: Since 1 year ≈ 52 weeks:
    T=0.02×52=1.04weeks.
    Additional Information: 1. Residence Time: Indicates how long a pollutant remains in the atmosphere before being removed.
    2. Short Residence Time: Pollutants are rapidly removed, showing localized impacts (e.g., particulate matter).
    3. Long Residence Time: Persistent pollutants like CO₂ cause global impacts.
    4. Flux Sources: Include natural processes (volcanic emissions, forest fires) and anthropogenic emissions (fossil fuel combustion).
    5. Mixing Ratio: Expresses the proportion of a gas relative to the total atmospheric mass.

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