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Which of the following was the main defect of Dobereiner's triad?
Question

Which of the following was the main defect of Dobereiner's triad?

A.

He arranged the three elements according to their increasing atomic masses.

B.

He was unable to form triads of more than three elements.

C.

He found some periodicity in the properties of triplets.

D.

The elements of a triad have some similarities in their properties.

Correct option is B

Sol: The correct answer is (b) He was unable to form triads of more than three elements.

Key Points:

  • The main defect of Dobereiner's triads was that he was unable to extend his method to include all known elements.
  • His classification was limited to only a few triads, as not all elements could be grouped into sets of three with similar properties and a pattern in atomic masses.
  • This limitation made his system incomplete and inadequate for classifying the growing number of elements discovered at the time.​

Information booster:

Dobereiner's Triads:

  • Definition: Dobereiner grouped elements into triads with similar properties and increasing atomic masses.
  • Atomic Mass Rule: The atomic mass of the middle element is the average of the other two.
  • Examples: Lithium-Sodium-Potassium, Calcium-Strontium-Barium, Chlorine-Bromine-Iodine.
  • Periodic Properties: Elements in a triad show gradual changes in properties like density and reactivity.
  • Limitations: Could only group a few elements; many did not fit into triads.
  • Significance: Laid the foundation for the modern periodic classification of elements.

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