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Which of the following indicator used in determination of hardness?
Question

Which of the following indicator used in determination of hardness?

A.

EBT

B.

Phenolphthalein

C.

Methyl orange

D.

Thymol blue

Correct option is A

The correct answer is (a) EBT

Explanation:

  • EBT stands for Eriochrome Black T, a complexometric indicator.
  • It is used in the EDTA titration method to determine the total hardness of water.
  • Hardness is caused by the presence of Calcium ($Ca^{2+}$) and Magnesium ($Mg^{2+}$) ions.
  • EBT forms a wine-red complex with these metal ions.
  • As EDTA is added, it displaces EBT, and at the endpoint, the solution turns from wine-red to steel blue.

Information Booster:
  • The titration is usually performed at a pH of 10 using an ammonia buffer.
  • Water hardness is typically expressed in terms of $CaCO_3$ equivalents.

Additional Knowledge:
Phenolphthalein (Option b)
  • Used for acid-base titrations; turns pink in basic solutions.

Methyl orange (Option c)
  • Used for acid-base titrations; turns red in acidic and yellow in basic solutions.

So the correct answer is (a)

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