Correct option is A
1.
Hardness of Water:
· Hardness of water is caused by the presence of divalent or trivalent cations, such as Ca2+, Mg2+, and Fe3+. These ions react with soap and form insoluble precipitates, leading to "hardness."
2.
Contributors to Hardness:
·
Ca2+
: A primary contributor to water hardness, typically from dissolved calcium salts (e.g., calcium carbonate).
·
Mg2+
: Another major contributor, usually from magnesium salts.
·
Fe3+
: Contributes to hardness if present in water as it forms insoluble hydroxides and carbonates.
3.
Non-Contributors to Hardness:
·
K+
(Potassium): Does not contribute to hardness as it is monovalent and highly soluble.
·
Na+
(Sodium): Also monovalent and does not form insoluble precipitates with soap. Sodium salts are associated with soft water.
Information Booster: 1. Types of Hardness:
· Temporary Hardness: Caused by bicarbonates of Ca2+ and Mg2+. Can be removed by boiling.
· Permanent Hardness: Caused by sulfates and chlorides of Ca2+, Mg2+, and Fe3+. Cannot be removed by boiling.
2. Monovalent vs. Divalent Ions:
· Monovalent ions (K+) do not contribute to hardness.
· Divalent or trivalent ions (Ca2+, Mg2+, Fe3+) contribute to hardness.
3. Applications:
· Understanding hardness is critical for water treatment, boiler maintenance, and preventing scaling in pipelines.
Thus,
K+
and Na+ do not contribute to the hardness of water.