Question

__________ make an isomeric pair.

A.

Butane and 2 – methyl propane

B.

Propane and butane

C.

Propane and 2 – methyl propane

D.

Butane and 2 – ethyl butane

Correct option is A

The correct answer is (a) Butane and 2-methylpropane

Explanation:

  • Butane (C₄H₁₀) is a straight-chain alkane with four carbon atoms.
  • 2-Methylpropane (C₄H₁₀), also known as isobutane, is a branched-chain alkane with the same molecular formula (C₄H₁₀) but a different structure.

Since both compounds have the same molecular formula (C₄H₁₀) but different structural arrangements, they are structural isomers.

Why the other options are incorrect:

  • b. Propane and Butane: These compounds have different molecular formulas (C₃H₈ for propane and C₄H₁₀ for butane), so they are not isomers.
  • c. Propane and 2-methylpropane: Propane has the formula C₃H₈, while 2-methylpropane (a branched isomer of butane) has C₄H₁₀. They have different molecular formulas, so they are not isomers.
  • d. Butane and 2-ethylbutane: Butane (C₄H₁₀) and 2-ethylbutane (C₆H₁₄) have different molecular formulas, so they are not isomers.


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