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In which of the following groups do all me hydrocarbons NOT belong to the same homologous series?
Question

In which of the following groups do all me hydrocarbons NOT belong to the same homologous series?

A.

C3H6,C5H10,C7H14 C_3 H_6,C_5 H_{10},C_7 H_{14}​​

B.

C2H2,C3H4,C4H6 C_2 H_2,C_3 H_4,C_4 H_6​​

C.

CH4,C2H6,C3H6 CH_4,C_2 H_6,C_3 H_6​​

D.

C2H4,C3H6,C4H8 C_2 H_4,C_3 H_6,C_4 H_8​​

Correct option is C

Sol: The correct answer is (c) CH4,C2H6,C3H6CH_4,C_2 H_6,C_3 H_6

Key Points:

(1) C3H6,C5H10,C7H14C _3​ H _6​ ,C _5​ H _{10}​ ,C _7​ H _{14}​ -

General formula: CnH2nC_nH_{2n}

This is the homologous series of alkenes.

All belong to the same series

(2) C2H2,C3H4,C4H6C _2​ H _2​ ,C _3​ H _4​ ,C _4​ H _6​

General formula: CnH2n2C_nH_{2n-2}

This is the homologous series of alkynes.

All belong to the same series

(3) CH4,C2H6,C3H6CH _4​ ,C _2​ H _6​ ,C _3​ H _6​

​​CH4CH_4 : General formula CnH2n+2C_nH_{2n+2} (alkane)

C2H6C _2​ H _6: General formula CnH2n+2C _n​ H _{2n+2} (alkane)

C3H6C _3​ H _6: General formula CnH2nC_nH_{2n} (alkene)

​Do not belong to the same series

(4) C2H4,C3H6,C4H8C _2​ H _4​ ,C _3​ H _6​ ,C _4​ H _8​ 

​General formula: CnH2nC_nH_{2n}

This is the homologous series of alkenes.

All belong to the same series

Reason- CH4CH_4 and C2H6C _2​ H _6 are alkanes, whereas C3H6C_3H_6 is an alkene​

CnH2nC_nH_{2nThis is the homologous series of alkenes.

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