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Which alkyne will produce aldehyde by hydration in presence of HgSO4 and H2SO4?
Question

Which alkyne will produce aldehyde by hydration in presence of HgSO4 and H2SO4?

A.

Hex-2-yne

B.

Ethyne

C.

But-2-yne

D.

Propyne

Correct option is B

The correct answer is (B) Ethyne

Explanation:

Ethyne (acetylene) undergoes hydration in the presence of mercury(II) sulfate (HgSO₄) and sulfuric acid (H₂SO₄) to produce acetaldehyde (CH₃CHO). This reaction involves a Markovnikov addition, where the water adds to the alkyne, resulting in the formation of an aldehyde.

Information Booster:
  1. The reaction is known as hydroboration-oxidation of alkynes.

  2. In the presence of HgSO₄ and H₂SO₄, Ethyne undergoes Markovnikov's rule for the addition of water.

  3. The product formed is acetaldehyde, a simple aldehyde.

  4. This reaction is commonly used in industrial processes for producing aldehydes.

  5. Ethyne (acetylene) is a simple alkyne that readily reacts with water under acidic conditions.

The reaction occurs through an intermediate enol, which tautomerizes to form the aldehyde.

Additional Information:
  • Hex-2-yne: Under the same conditions, it produces a ketone rather than an aldehyde.

  • But-2-yne: Similarly, this alkyne produces a ketone and does not yield an aldehyde.

  • Propyne: Like other alkynes, it also produces a ketone rather than an aldehyde under these conditions.

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