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Which statement is true regarding the exchangeable acidity in the soil chemistry?
Question

Which statement is true regarding the exchangeable acidity in the soil chemistry?

A.

An exchangeable acidity is derived from exchangeable Na+ cations

B.

Exchangeable acidity is derived from exchangeable Ca3+ cations

C.

Exchangeable acidity is derived from exchangeable Al3+ cations

D.

Exchangeable acidity is derived from exchangeable Al3+ anions

Correct option is C

The correct answer is: (C) Exchangeable acidity is derived from exchangeable Al³⁺ cations
Explanation:
Exchangeable acidity in soil refers to the acidity caused by exchangeable hydrogen (H⁺) and aluminum (Al³⁺) ions present in the soil colloid complex.
It is primarily due to exchangeable Al³⁺ cations, which can hydrolyze and release hydrogen ions (H⁺) into the soil solution, increasing soil acidity.
Aluminum plays a crucial role in acidic soils (pH < 5.5) by contributing to soil acidity through its hydrolysis reaction, forming Al(OH)²⁺ and releasing additional H⁺ ions.
Information Booster:
  • Higher levels of exchangeable Al³⁺ indicate a need for lime application to neutralize acidity.

  • Exchangeable Al³⁺ can be toxic to plants, inhibiting root growth and reducing crop productivity.

  • It is different from active acidity (H⁺ in soil solution) and residual acidity (H⁺ and Al³⁺ bound to organic matter and clay particles).

Knowledge Booster :
  • Exchangeable Na⁺ cations → they are associated with alkaline or sodic soils.

  • Exchangeable Ca³⁺ cations → Calcium (Ca²⁺, not Ca³⁺) is a basic cation that reduces soil acidity.

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