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Which of the following molecules has/have a cage-like structure? I. Diamond II. Graphite III. Fullerene
Question

Which of the following molecules has/have a cage-like structure?
I. Diamond
II. Graphite
III. Fullerene

A.

I, II and III

B.

Only II and III

C.

Only II

D.

Only III

Correct option is D

The correct answer is (d) Only III

Fullerene:

  • Fullerenes are molecules composed entirely of carbon atoms arranged in a cage-like structure.
  • The most common fullerene is C₆₀, also known as Buckminsterfullerene, which resembles a soccer ball.
  • These molecules have a hollow, spherical, ellipsoidal, or tubular shape.

Diamond:

  • Diamond has a tetrahedral crystal lattice structure, not a cage-like structure.
  • Each carbon atom is bonded to four other carbon atoms in a 3D network.

Graphite:

  • Graphite has a layered structure with carbon atoms arranged in hexagonal sheets, not a cage-like structure.
  • These sheets are held together by weak van der Waals forces.

Additional Information:

Why Fullerenes Have Cage-Like Structures:

  • Fullerenes form a closed geometry (spherical, tubular, or ellipsoidal), making them unique among carbon allotropes.
  • The structure is formed by a combination of pentagons and hexagons, creating a hollow, stable configuration.

Key Differences Between Carbon Allotropes:

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