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Which of the following electrolytes is used in the electrolyte refining of copper?
Question

Which of the following electrolytes is used in the electrolyte refining of copper?

A.

Sodium sulphate 

B.

Cuprous chloride

C.

Copper Oxide

D.

Copper sulphate

Correct option is D

Correct Answer: (D) Copper sulphate

Explanation:

  • In the electrolytic refining of copper, an aqueous solution of copper sulphate (CuSO₄) is used as the electrolyte.
  • The process involves:
    1. Anode: Impure copper, which acts as the source of copper ions.
    2. Cathode: Pure copper, where copper ions from the solution deposit as pure copper.
    3. Electrolyte: Copper sulphate solution provides the copper ions for the electrochemical process.
  • At the anode:

Cu (impure)→Cu2++2e

  • At the cathode:

Cu2++2e−→Cu (pure)

Why Other Options Are Incorrect:

  • (Sodium sulphate): Not used in copper refining; it does not provide copper ions.
  • (Cuprous chloride): Not a common electrolyte for copper refining.
  • (Copper oxide): It is not soluble in water to act as an effective electrolyte in this process.

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