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Which ion reduces at the cathode during electrolysis of fresh brine solution?
Question

Which ion reduces at the cathode during electrolysis of fresh brine solution?

A.

Cl⁻

B.

H+

C.

OH⁻

D.

Na+

Correct option is B

Correct option (b), H+

During the electrolysis of fresh brine solution (which is an aqueous solution of sodium chloride, NaCl), the ion that reduces at the cathode is the hydrogen ion (H⁺).

Information Booster:

  • Brine Solution is made up of water (H₂O) and sodium chloride (NaCl). When electricity is passed through the brine.
  • At the cathode (negative electrode)
  • At the anode (positive electrode): Chloride ions (Cl⁻) are oxidized to form chlorine gas (Cl₂).
  • Hydrogen ions (H⁺)
  • hydrogen gas (H₂)

  • Reduction of hydrogen ions (H⁺):

2H++2eH2(g)2H^+ + 2e^- \rightarrow H_2(g) 

  • ​Reduction of sodium ions (Na⁺)

Na++eNa(s)Na^++e^- \rightarrow Na(s)

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