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What is the change in entropy when water is vaporized at 100°C. Latent heat of vaporization of water may be taken as 2238 kJ/kg.
Question

What is the change in entropy when water is vaporized at 100°C. Latent heat of vaporization of water may be taken as 2238 kJ/kg.

A.

22.38 kJ/kg K

B.

2.238 kJ/kg K

C.

6 kJ/kg K

D.

100 kJ/kg K

Correct option is C

Given: Latent heat of vaporization L=2238 kJ/kg Temperature T=100C=373 KSol.The change in entropy during a phase change at constant temperature is given by:ΔS=QrevTWhere:Qrev=L=2238 kJ/kg=2238000 J/kgT=373 KNow, compute:ΔS=22380003736001.6 J/kgK=6.002 kJ/kgK\begin{aligned}&\textbf{Given:} \\&\bullet\ \text{Latent heat of vaporization } L = 2238\, \text{kJ/kg} \\&\bullet\ \text{Temperature } T = 100^\circ C = 373\, \text{K} \\[1em]&\textbf{Sol.} \\&\text{The \textbf{change in entropy} during a \textit{phase change at constant temperature} is given by:} \\&\Delta S = \frac{Q_{\text{rev}}}{T} \\[1em]&\text{Where:} \\&Q_{\text{rev}} = L = 2238\, \text{kJ/kg} = 2238000\, \text{J/kg} \\&T = 373\, \text{K} \\[1em]&\text{Now, compute:} \\&\Delta S = \frac{2238000}{373} \approx 6001.6\, \text{J/kg} \cdot \text{K} = 6.002\, \text{kJ/kg} \cdot \text{K}\end{aligned}​​

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