Correct option is C
The correct use of present tense is "She spends all her money on make-up in order to look beautiful."
Error identification: The incorrect forms "spended" and "had spend" are used instead of "spent" and "had spent," respectively. The phrase "has spend" is also incorrect because it should be "has spent."
Grammatical Rule used: The verb "spend" in the present tense for a singular subject should be "spends."