Correct option is A
The correct one-word for the given group of words is (a) Infallible.
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Infallible: Someone who is incapable of making mistakes or being wrong. (अचूक, जो गलती न करे)
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Example: The scientist believed his theory was infallible until new evidence proved otherwise.
Meanings of the given other options:
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Inimitable: Impossible to imitate or copy (अद्वितीय, अनुपम)
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Impregnable: Impossible to be defeated or broken into (अभेद्य)
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Inevitable: Certain to happen, unavoidable (अनिवार्य)