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​Phosphofructokinase catalyses one of the regulatory steps in glycolysis. Which one of the following metabolic changes leads to the activation of phos
Question

Phosphofructokinase catalyses one of the regulatory steps in glycolysis. Which one of the following metabolic changes leads to the activation of phosphofructokinase?

A.

Increased ATP concentration

B.

Decreased AMP concentration

C.

High citrate levels

D.

Increased fructose 2,6-bisphosphate concentration

Correct option is D

Explanation-

PFK-1 catalyzes the conversion of fructose-6-phosphate to fructose-1,6-bisphosphate. This is a rate-limiting and highly regulated step in glycolysis. Its activity is controlled by the energy needs of the cell through allosteric regulation by certain metabolites.

​Option d: Increased fructose 2,6-bisphosphate concentration
It increases the enzyme's affinity for fructose-6-phosphate. It also reduces ATP’s inhibitory effect. F2,6BP levels are hormonally regulated (e.g., by insulin and glucagon), linking glycolysis to the body’s metabolic state.

Incorrect options-

Option a: Increased ATP concentration
When ATP levels are high, it binds to a regulatory site (not the active site) of PFK-1 and inhibits its activity. This is a form of feedback inhibition, where high energy status of the cell slows down glycolysis.
Option b: Decreased AMP concentration
When energy is low, AMP levels rise and stimulate PFK-1 to speed up glycolysis for energy production. So, if AMP is decreased, this activation is lost
Option c: High citrate levels
High citrate allosterically inhibits PFK-1, acting as a feedback inhibitor and slowing down glycolysis.

Final answer - Option d - Increased F2,6BP strongly activates PFK-1 →  Correct answer

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