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Oxidation number of Mn in KMnO4KMnO_4KMnO4​ is:​
Question

Oxidation number of Mn in KMnO4KMnO_4 is:​

A.

-7

B.

+7

C.

-6

D.

+6

Correct option is B

The correct answer is (B) +7

Explanation:
In the compound KMnO₄ (Potassium permanganate), the oxidation number of manganese (Mn) can be determined by considering the charges of the other elements in the compound.

  • Potassium (K) always has an oxidation number of +1.

  • Oxygen (O) in most compounds, including KMnO₄, typically has an oxidation number of -2.

Let the oxidation number of manganese (Mn) be x. The total oxidation number of the compound must equal zero since KMnO₄ is neutral.

The sum of oxidation numbers can be written as:

Oxidation number of K+Oxidation number of Mn+Oxidation number of 4 O=0\text{Oxidation number of K} + \text{Oxidation number of Mn} + \text{Oxidation number of 4 O} = 0

Substituting the known values:

(+1)+x+4(2)=0(+1)+x+4(−2)=0

1+x8=01+x−8=0

x7=0x−7=0

x=+7x=+7​​​​​

Thus, the oxidation number of manganese in KMnO₄ is +7.

Information Booster:

  • Oxidation number is a concept used to keep track of the electrons involved in redox reactions.

  • In KMnO₄, manganese is in its highest oxidation state of +7.

  • Potassium permanganate is commonly used as an oxidizing agent in redox reactions.

  • The compound KMnO₄ is widely used in various chemical processes, including disinfection, bleaching, and as a titrant in redox titrations.

  • Manganese compounds exhibit a variety of oxidation states, with +7 being the highest in KMnO₄.

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