Question

In the following reaction, the product is

A.

o-nitro benzoic acid

B.

p-nitro benzoic acid

C.

m-nitro benzoic acid

D.

Benzene

Correct option is C

In nitration of benzoic acid, the –COOH group is a meta-directing group due to its electron-withdrawing nature.
When nitrated using conc. HNO₃ and conc. H₂SO₄, the nitro group enters the meta-position relative to the carboxylic acid group. Therefore, the major product is m-nitro benzoic acid.

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