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In the following compounds, what is the increasing order of their reactivity towards nucleophilic addition reactions? Benzaldehyde, p-Tolualdehyde,
Question

In the following compounds, what is the increasing order of their reactivity towards nucleophilic addition reactions?
Benzaldehyde, p-Tolualdehyde, p-Nitrobenzaldehyde, Acetophenone

A.

Benzaldehyde < p- Tolualdehyde < p-Nitrobenzaldehyde < Acetophenone

B.

Acetophenone < Benzaldehyde < p-Tolualdehyde < p-Nitrobenzaldehyde

C.

Acetophenone < p-Tolualdehyde < Benzaldehyde < p-Nitrobenzaldehyde

D.

Benzaldehyde < Acetophenone < p-Tolualdehyde <p-Nitrobenzaldehyde

Correct option is C

Order of reactivity: acetophenone < p-tolualdehyde < benzaldehyde < p-nitrobenzaldehyde. Due to hyperconjugation, methyl group in p-tolualdehyde is electron releasing because of which the positive charge on carbonyl carbon decreases.

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