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In industrial settings, Freon-12 is most commonly manufactured by which chemical reaction?
Question

In industrial settings, Freon-12 is most commonly manufactured by which chemical reaction?

A.

Wurtz reaction

B.

Swarts reaction

C.

Elimination reaction

D.

Substitution reaction

Correct option is B

Sol.

Correct Ans is (B) Swarts reaction

Explanation:

Freon-12 (also known as dichlorodifluoromethane, CCl₂F₂) is most commonly manufactured by the Swarts reaction, which is a fluorination reaction. In this process, a metal halide (usually Aluminum chloride) is used to substitute chlorine atoms in carbon tetrachloride (CCl₄) with fluorine atoms, producing Freon-12.

Information Booster:

  • Swarts reaction involves the substitution of chlorine with fluorine, often using a fluorine-containing compound like HF or SbF₅.
  • The Swarts reaction is crucial in producing various halogenated compounds, including refrigerants and propellants like Freon-12.

Additional Information:

  • (A) Wurtz reaction: This is a coupling reaction of alkyl halides with sodium to form alkanes, and it does not relate to the production of Freon-12.
  • (C) Elimination reaction: This type of reaction involves the removal of a small molecule (like water or hydrogen halide) from a substrate and is not related to Freon-12 synthesis.
  • (D) Substitution reaction: While Swarts reaction is a substitution reaction, the term substitution reaction is too broad, and Swarts specifically refers to the fluorination process used in making Freon-12.

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