Correct option is C
1. Statement I:
· Correct.
· During the Antarctic winter, special vortex weather conditions (polar stratospheric clouds) lead to denitrification, which removes nitrogen-containing compounds. This allows the conversion of inactive chlorine compounds, such as HCl and ClONO2 , into active chlorine molecules like Cl2 and ClO. These active chlorine compounds are responsible for ozone depletion when sunlight returns in spring.
2. Statement II:
· Incorrect.
· HCl and ClONO2 are not active chlorine compounds. Instead, they are reservoir compounds that store chlorine in an inactive form. Active chlorine compounds include Cl2 and ClO, which directly participate in ozone depletion.
Thus, the correct answer is (c) Statement I is correct, but Statement II is incorrect.
Information Booster: 1. Key Processes in Ozone Depletion:
· Denitrification: Removal of nitrogen oxides (NOx) due to polar stratospheric clouds.
· Activation of Chlorine: Conversion of inactive chlorine compounds (HCl, ClONO2) into active forms (Cl2, ClO) under polar vortex conditions.
2. Active vs. Inactive Chlorine Compounds:
· Active: Cl2, ClO (destroy ozone).
· Inactive (reservoir): HCl, ClONO2 (do not directly harm ozone).
3. Role of Polar Vortex:
· Isolates the Antarctic stratosphere, creating extremely low temperatures for polar stratospheric cloud formation.
Additional Knowledge: Statement I (Correct):
· Explains the role of polar vortex and denitrification in chlorine activation, which drives ozone depletion in the Antarctic region.
Statement II (Incorrect):
· HCl and ClONO2 are chemically stable reservoir species, not active participants in the catalytic destruction of ozone.