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Given below are two statements: Assertion (A) and Reason (R). Assertion (A): Soil acidity can be caused due to loss of Calcium & Magnesium salts i
Question

Given below are two statements: Assertion (A) and Reason (R). Assertion (A): Soil acidity can be caused due to loss of Calcium & Magnesium salts in areas of high rainfall. Reason (R): CO₂ formed during respiration reacts with water to form carbonic acid which converts bases into soluble forms that are lost through leaching.

A.

Both (A) and (R) are correct and (R) is the correct explanation of (A)

B.

Both (A) and (R) are correct but (R) is NOT the correct explanation of (A)

C.

(A) is correct but (R) is not correct

D.

(A) is not correct but (R) is correct

Correct option is A

The correct answer is (A) Both (A) and (R) are correct and (R) is the correct explanation of (A)
Explanation: 

Assertion (A):
High rainfall leads to the leaching of basic cations like Ca2+ and Mg2+.
As these bases are removed from the soil exchange complex, they are replaced by acidic ions such as H+ and Al3+, resulting in soil acidity.

Reason (R):
Microbes and plant roots release CO2 ​ during respiration. This CO2dissolves in soil water to form H2CO3 ​ (carbonic acid). The carbonic acid dissociates to release H+ ions, which displace Ca2+ and Mg2+ from soil particles, making them soluble and susceptible to leaching.

• Since the reason provides the direct chemical mechanism for the process mentioned in the assertion, (A) is the correct choice.

Information Booster:
• Acid soils are usually reclaimed by adding 'lime' (Calcium carbonate), which neutralizes $H^{+}$ and replaces $Al^{3+}$ with $Ca^{2+}$.

Additional Knowledge:
• Soil pH: A measure of the acidity or alkalinity of the soil. A pH below 7 is acidic.
• Aluminum Toxicity: In very acidic soils (pH < 5.0), Aluminum becomes soluble and is toxic to most plant roots.

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