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​Given below are certain statements regarding light absorption by the chlorophyll pigment molecule in a green leaf:A. The absorption of a photon by a
Question


Given below are certain statements regarding light absorption by the chlorophyll pigment molecule in a green leaf:

A. The absorption of a photon by a pigment molecule converts it from its lower state to an excited state.

B. Internal conversions or relaxations of pigments convert higher excited states to the lowest excited state, with a concomitant loss of energy as heat.

C. The light re-emitted from the lowest excited state of the chlorophyll molecule is fluorescence.

D. Red light absorption by the chlorophyll molecule results in a higher excitation state relative to blue light absorption.

Which one of the following combinations is correct?


A.

A, B, and C

B.

A, B, and D

C.

B, C, and D

D.

A, C, and D

Correct option is A


Explanation:

Statement A: Correct

  • Absorption of light (photon) excites a pigment molecule.
  • When chlorophyll absorbs a photon, an electron moves from the ground state to an excited state.
  • The energy difference between these states is equal to the absorbed photon's energy.
  • This is the fundamental process in photosynthesis.

Statement B: Correct

  • After excitation, electrons return to the lowest excited state before releasing energy.
  • This process is known as internal conversion or relaxation.
  • The energy lost is dissipated as heat, making it a non-radiative transition.
  • It ensures that photochemical reactions occur from the lowest excited state.

Statement C: Correct

  • When chlorophyll molecules return to the ground state from their lowest excited state, they emit energy as fluorescence (a lower-energy photon).
  • Chlorophyll fluorescence occurs at a longer wavelength (red region) due to energy loss as heat.
  • This is important in measuring photosynthetic efficiency in plants.

Statement D: Incorrect

  • Blue light has more energy than red light because energy is inversely proportional to wavelength (E = hν = hc/λ).
  • Chlorophyll absorbs blue light (shorter wavelength) at a higher energy level than red light.
  • Thus, blue light excites electrons to a higher state than red light, making this statement incorrect.

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