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    Consider an ideal gas system. For an exothermic reaction occurring at constant pressure, how does the enthalpy change?
    Question

    Consider an ideal gas system. For an exothermic reaction occurring at constant pressure, how does the enthalpy change?

    A.

    Negative

    B.

    Path dependent

    C.

    Zero

    D.

    Positive

    Correct option is A

    The correct answer is (a) Negative.
    • For a reaction occurring at constant pressure, the enthalpy change (ΔH) equals the heat exchanged (qₚ).
    • In an exothermic reaction, heat is released to the surroundings, so qₚ < 0 and therefore ΔH is negative.
    Information Booster:
    • Enthalpy is a state function, independent of the path taken.
    • For an ideal gas, enthalpy depends only on temperature.
    • ΔH < 0 → Exothermic reaction
    • ΔH > 0 → Endothermic reaction
    Additional Knowledge:
    • At constant pressure: ΔH = qₚ
    • At constant volume: ΔU = qᵥ
    • The concept of enthalpy was introduced by Heike Kamerlingh Onnes in 1909.

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