Correct option is A
Check each options:
Logic:
1st letter − 5 = 3rd letter
2nd letter − 6 = 4th letter

Option (A): GK – BF
G − 5 = B
K − 6 = E (but 4th letter is F) → does not follow the logic
Option (B): SW – NQ
S − 5 = N
W − 6 = Q → follows the logic
Option (C): UY – PS
U − 5 = P
Y − 6 = S → follows the logic
Option (D): LP – GJ
L − 5 = G
P − 6 = J → follows the logic
Thus, the letter-cluster pair that does NOT belong to the group is (A).