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Arrange the following substances in the increasing order of their heat capacity at standard temperature and pressure: (A) Ice (B) Water (C) Air (D) Dr
Question

Arrange the following substances in the increasing order of their heat capacity at standard temperature and pressure:

(A) Ice

(B) Water

(C) Air

(D) Dry sand

Options:

A.

(B), (A), (D), (C)

B.

(A), (B), (C), (D)

C.

(C), (D), (A), (B)

D.

(D), (C), (A), (B)

Correct option is D

Introduction:

  • Heat capacity refers to the amount of heat energy required to raise the temperature of a substance.
  • The specific heat capacity) is the amount of heat energy required to raise the temperature of a unit mass of a substance by one degree Kelvin (or Celsius).
  • It requires arranging the substances in increasing order of this value, which determines how much heat they can store.
  • Substances with lower specific heat capacity heat up quickly, while those with higher values require more energy for the same temperature change.

Information Booster:

  • The specific heat capacity (c) is the amount of heat energy required to raise the temperature of a unit mass of a substance by one degree Kelvin (or Celsius). 
  • Dry Sand<Air<Ice<Water\text{Dry Sand} < \text{Air} < \text{Ice} < \text{Water}
  • To arrange these common substances, we use their approximate specific heat capacities (cp)inJkg1K1nearSTP(25Cand1 atmc_p) in \text{J}\cdot\text{kg}^{-1}\cdot\text{K}^{-1} near STP (25^\circ\text{C} and 1 \text{ atm}
Substance
Specific Heat Capacity (cp​) (J⋅kg−1⋅K−1)
Rank
(D) Dry Sand / Silicon DioxideSiO2 \text{SiO}_2​)
780800\approx 780 - 800​​
1 (Lowest)
(C) Air (Dry, Constant Pressure)
1,005\approx 1,005​​
2
(A) Ice(at 0CIce (\text{at } 0^\circ\text{C}​)
2,0902,100\approx 2,090 - 2,100​​
3
(B) Liquid Water (at 25C\text{at } 25^\circ\text{C}​​
4,184\approx 4,184​​
4 (Highest)

Analysis of Order:

  • Dry Sand (D): As a solid mineral (mainlySiO2 \text{SiO}_2​), sand has a low specific heat capacity. This is why sand heats up very quickly during the day and cools down quickly at night.
  • Air (C): Air (a mixture of gases) has a relatively low specific heat capacity compared to solids and liquids, though it's higher than many dense solids.
  • Ice (A): The specific heat capacity of solid water is roughly half that of liquid water, as the crystal lattice structure limits the ways in which the molecules can absorb energy.
  • Liquid Water (B): Water has the highest specific heat capacity among common, non-metallic liquids. This is primarily due to the extensive hydrogen bonding between its molecules, which requires a large amount of energy to break/agitate before the overall kinetic energy (temperature) increases.

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