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According to Lewis concept, an acid is
Question

According to Lewis concept, an acid is

A.

proton acceptor

B.

electron pair acceptor

C.

proton donor

D.

electron pair donor

Correct option is B

The correct answer is (b) Electron pair acceptor

  • The Lewis concept, proposed by G.N. Lewis in 1923, defines acids and bases based on electron pairs rather than protons.

  • A Lewis acid is a species that accepts an electron pair, while a Lewis base is one that donates an electron pair.

  • This definition is broader than the Brønsted-Lowry concept and includes non-protonic acids like metal ions and electron-deficient molecules.

  • Example:

    BF3+NH3→F3B←NH3\text{BF}_3 + \text{NH}_3 \rightarrow \text{F}_3\text{B} \leftarrow \text{NH}_3BF3+NH3F3BNH3
  • Here, BF₃ (electron-deficient) is the Lewis acid, and NH₃ (donates electron pair) is the Lewis base.

Information Booster:
Lewis Acid: Accepts an electron pair (e.g., BF₃, AlCl₃, Fe³⁺).
Lewis Base: Donates an electron pair (e.g., NH₃, OH⁻, H₂O).
• This theory explains acid-base reactions without involving protons (H⁺).
• Useful in understanding coordination chemistry and catalysis.
• All Brønsted-Lowry acids are Lewis acids, but not all Lewis acids are Brønsted-Lowry acids.
• Molecules with vacant orbitals often act as Lewis acids.

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